Abstract
The room temperature single-crystal X-ray structure determination of the title compound, PrI3·9H2O, better represented as [Pr(OH2)9]I3, shows unequivocally that it belongs to the structure type preferably adopted by hydrates of the lighter rare earth iodides (La–Ho). The praseodymium cation is coordinated by nine water molecules in the form of a tricapped trigonal prism with the metal atom situated on a site of crystallographic symmetry mm2.
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