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Abstract
The complex formation equilibria of [Pd(FLX)(H2O)2]2+, where FLX = the drug fluoxetine, with the bio-ligands (L), glycine, serine, cysteine, histidine, glycylglycine and glycylvaline, were studied and their formation constants were determined. Stoichiometries and stability constants of the complexes were determined at 25 °C and at constant 0.10 mol·dm−3 NaNO3 ionic strength. The concentration distribution of the complexes in solution was evaluated. Palladium(II) complexes were synthesized and characterized by the 1H NMR and electronic spectral studies. The structures consist of monomeric units in which the Pd(II) atoms exhibit square planar geometry.
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