Abstract
Abstract The overall formation constants of cadmium- and zinc-halide complexes in acetonitrile were determined by potentiometric titration using a saturated metal amalgam indicator electrode. The effect of ion-pair formation was taken into consideration to elucidate the free halide ion concentration in the experiments. The values of logβ3 and logβ4 for cadmium-halide complex were found to be: I−, 22.4 and 26.5; Br−, 25.3 and 29.8; Cl−, 29.2 and 34.0. The values for zinc-chloride complex were 20.1 and 23.4.
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