Abstract
The formation constants of mixed ligand complexes of MII (M = Ni, Zn or Cd) with β-alaninehydroxamic acid (β-Alaha) as primary ligand (A) and ethylenediamine (en) as secondary ligand (B) have been determined potentiometrically [298 K, μ = 0.2 (KCl)]. The formation constants for binary systems of β-alaninehydroxamic acid and ethylenediamine were determined under identical experimental conditions. The pH-titration data were analysed using the SUPERQUAD computer program. The relative stability of each ternary complex was compared to that of its corresponding binary complex in terms of log X values.
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