Abstract
An investigation of the potentiodynamic polarization behavior of ten high-purity Fe-Ni alloys has shown that the anodic behavior in the active region of dissolution is controlled by Fe in alloys containing up to and including 50at.%Ni. The Fe is believed to dissolve initially in the + 2 state, then the + 3 state; whereas, Ni is believed to dissolve in the + 3 state at all anodic potentials in the active region. The cathodic polarization data indicate that the evolution of hydrogen is a monatomic process dependent on the crystallographic structure of the alloy.
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