Abstract
The factors have been considered which can lead to a discrepancy between the difference of the potentials of zero charge and the difference of the work functions. It has been shown that some discrepancies are eliminated if instead of the potentials of zero charge, we compare the potentials corresponding to the same and sufficiently large negative electrode charge, thus ensuring the same interaction between the electrode surface and water dipoles. This method is however inapplicable to metal phases of variable composition if the pzc of their components differ significantly.
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