Abstract
The method of potential-step electrolysis followed by linear potential-sweep voltammetry is considered theoretically. It is shown that, for a reversible electrode reaction without kinetic complications, the current—potential curve obtained during the linear potential-sweep is closely connected with the Ševčik—Randies P-function of normal linear-sweep voltammetry. Analytical implications are pointed out, while the presence of kinetic complications and the effect of finite electrode volume are briefly discussed.
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