Abstract

Large quantities of solid wastes, including gangue (waste rock) have been added to the goafs in China’s coal mines as backfill. In this study, the mineral and chemical compositions of gangue from the No. 12 coal mine of the Pingdingshan Coal Group were investigated to determine potential pollution concerns, and the behaviour of contaminants in the gangue, such as salts, alkali metals, and alkaline earth metals, was explored using static immersion tests. COMSOL Multiphysics was used to study contaminant migration. The concentration and diffusion distance of metal ions were found to increase over time; this was negatively correlated with gangue particle size. Acidic environments promoted the dissolution of Ca, Fe, Mn, Na, Zn, Pb, and Be, while in alkaline environments, Se dissolution was accelerated.

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