Potential of Sargassum wightii biomass for copper(II) removal from aqueous solutions: Application of different mathematical models to batch and continuous biosorption data

Abstract

This paper reports biosorption of copper(II) ions onto Sargassum wightii biomass in batch and continuous mode of operation. Batch experiments were fundamentally aimed to determine the favorable pH for copper(II) biosorption. Langmuir model was used to describe the copper(II) biosorption isotherm and maximum uptake of 115mg/g was obtained at pH 4.5. Continuous experiments in a packed column (2cm i.d. and 35cm height) were performed to study the influence of bed height, flow rate and inlet solute concentration on copper(II) biosorption. The highest bed height (25cm), lowest flow rate (5ml/min) and highest inlet Cu(II) concentration (100mg/l) resulted in highest copper(II) uptake of 52.6mg/g, compared to other conditions examined. Column data obtained at different conditions were described using the Thomas, Yoon–Nelson and modified dose–response models. All three models were able to predict breakthrough curves; in particular, the breakthrough curve prediction by the Thomas and Yoon–Nelson models were found to be very satisfactory. Also, the well-established design model, the Bed depth–service time (BDST) model was used to analyze the experimental data. The BDST model plot at 5ml/min (flow rate) and 100mg/l (inlet solute concentration) was used to predict bed depth–service time data at different conditions. The BDST model predicted values always coincide with experimental values with high correlation coefficients.