Abstract
Macro-defect-free (MDF) materials comprise a “hot topic” example in the field of cement-based materials and composites. The methods of MAS-NMR and thermal analysis gave key data for monitoring the scope of Al–O–P cross-links both in virgin MDF test pieces and in those exposed to moisture. The increased contents of calcium aluminate hydrates, calcium silicate hydrates and CaCO 3 in moisture-attacked (as opposed to virgin) MDF probes have been detected by these methods. The controlling feedback from cross-links and interfaces to the extent of secondary interactions of MDF materials with out-door atmospheric humidity is evident. Data on both the next-nearest-neighbour (NNN) interactions and the thermal stability of cross-linked interfaces show that for MDF materials chemical knowledge is crucial to (i) procedure design; Al–O–P cross-linking is the key nano-scale aspect of the MDF formation process and (ii) exploitation; interfaces comprise compact and stable regions in which Al–O–P cross-links support moisture resistance in the MDF materials.
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