Abstract

Fertilization is an important cause of groundwater contamination with nitrate in agricultural soils. The objectives of the present work were: (i) to quantify the nitrate leaching in two fertilized and irrigated soils of the Pampas Region, Argentina; (ii) to test the ability of the NLEAP model to predict residual and leached nitrate in those soils. The soils were a Typic Hapludoll and a Typic Argiudoll. The treatments were: natural grassland never ploughed or fertilized; maize with a short history of fertilization; maize with a long history of fertilization; irrigated maize with a long history of fertilization. Both sites were sampled after harvest in two consecutive years to a 3 m depth. Residual nitrate and potential losses below 150 cm were estimated by NLEAP model. The average amount of nitrate (NO 3-N), including values of all treatments, in the upper layer (0–1.5 m) was 128 kg NO 3-N ha −1 in the first sampling date and was consistently lower in the second sampling date (38 kg NO 3-N ha −1). In the deeper layer (1.5–3 m) these values were 80 and 28 kg NO 3-N ha −1 for the first and second sampling date, respectively. Differences between the non-fertilized and the fertilized treatments were significantly smaller in the second sampling date. Obtained results suggest that the rainfall previous to the first sampling was not enough to displace nitrate below 3 m depth. The afterwards heavy rainfall leached nitrate previously accumulated in the soil. Complementary irrigation did not affect nitrate movements. Simulated residual and leached nitrate showed a high correlation with observed values. Nitrate leaching was more associated to rainfall regime and crop yields than to soil type. Simulated residual and leached nitrate showed a high correlation with measured values in both soils, which suggests that NLEAP was appropriate to predict soil nitrate leaching under the studied conditions.

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