Potential Impacts of Prunus domestica Based Natural Gum on Physicochemical Properties of Polyaniline for Corrosion Inhibition of Mild and Stainless Steel.

Abstract

The lack of an eco-friendly approach towards application of polyaniline as a coating material has been one of the most challenging tasks. Herein, the synthesis of green Prunus domestica gum grafted polyaniline (PDG-g-PANI) composite is reported by a cost-effective emulsion polymerization for application as an efficient anti-corrosion material for mild steel (MS) and stainless steel (SS) in a strong corroding environment. The composite formation was confirmed by Ultraviolet Visible (UV-Visible) and Fourier Transformed Infrared (FTIR) spectroscopies. X-ray diffraction data revealed the amorphous nature of the PDG-g-PANI. Scanning Electron Microscopic (SEM) images showed a bi-layered structure having a parent porous layer of PANI coated with afibrous layer of PDG. The solubility test confirmed the dissolution of PDG-g-PANI in common organic solvents such as acetone, ethanol, propanol, butanol, chloroform, N-Methyl-2-pyrrolidone, dimethyl sulfoxide, and the mixture of propanol and chloroform. The polarization curve, open circuit potential, electrochemical impendence spectroscopy (EIS), and gravimetric analysis were applied to investigate the corrosion protection behavior of the composite on MS and SS in 3.5% NaCl and 1 M H2SO4 solution. The PDG-g-PANI-coated MS exhibited 96% corrosion inhibition efficiency as compared to 86% and 43% for pristine PANI and PDG in 3.5% NaCl solution while PDG-g-PANI-coated SS showed 98% corrosion inhibition efficiency. Moreover, 99% and 96.6% corrosion protection was observed for PDG-g-PANI-coated MS and SS in 1 M H2SO4 solution. Gravimetric studies revealed that PDG-g-PANI coating can protect MS up to 93% for 14 days in salt solution while 97% corrosion inhibition efficiency was retained for 2 months in open air.