Abstract
The potential function has been constructed for internal rotation of the NO-group in (CH3)2CClNO, CH3CCl2NO, and their deuterium analogs. It has been established that the N=O bond in the cisCl conformer of CH3CCl2NO does not eclipse the C-Cl bond, rather forming an angle of approximately 30‡. It has been shown that a change in substitutent on the α-carbon atom may produce a substantial change in the form of the potential function of internal rotation (PFIR) of the NO group.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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