Potential enhancement in atmospheric new particle formation by amine-assisted nitric acid condensation at room temperature

Abstract

Atmospheric aerosol plays a critical role in global climate and public health. Recent laboratory experiments showed that new particle formation is significantly enhanced by rapid condensation of nitric acid and ammonia at low temperatures. Amines are derivatives of ammonia with a significant presence in the atmosphere. For example, the wide implementation of amine-based Post-Combustion Carbon Capture (PCCC) units may significantly increase the ambient alkanolamine and polyamine levels. Using thermodynamic simulations, the condensation of alkylamines, alkanolamines and polyamines with nitric acid at various temperatures was systematically evaluated. Alkylamines will condense with nitric acid at temperatures comparable to that of ammonia. However, with additional hydrogen bonding groups, alkanolamines and polyamines may condense with nitric acid at room temperature, suggesting a new potential pathway to remove these amines from the atmosphere. Our results suggest the potentially critical role of amines in the atmospheric new particle formation via condensation with nitric acid to rapidly grow freshly nucleated clusters over their critical size at a higher temperature than ammonia. The condensed amines and nitric acid can also facilitate water uptake by aerosol particles at low relative humidity, which may alter their subsequent atmospheric transformations.