Abstract
A set of potential energy constants was obtained for the SOF 4 molecule from the vibrational spectral data. The axial SF and equatorial SF stretching force constants are 5.5400 and 4.3950 md/Å, respectively. The mean square amplitudes of vibration also were determined from the potential energy constants by use of Cyvin's secular equation method. The root-mean-square amplitudes for the axial SF, equatorial SF, and SO distances are 4.060, 4.545, and 3.617 pm, respectively, (1 pm = 1 picometer = 10 −2Å).
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