Abstract
AbstractA vibrational analysis has been made for the XY7 type molecules and radicals which have the pentagonal bipyramidal structure belonging to the symmetry point group D5h. An orthonormalized set of symmetry coordinates satisfying the transformation properties has been constructed for XY7 type molecules. The elements of F and G matrices have been worked out and from these matrices the secular equations for the various irreducible representations have been deduced by means of Wilson's group theoretical method. A potential function consisting of the ordinary valence force terms and central force terms has been adopted for the evaluation of potential constants for Iodine heptafluoride.
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