Abstract

Here, we proposed a pin-to-liquid dielectric barrier discharge (DBD) structure that used a water-containing vessel body as a dielectric barrier for the stable and effective treatment of aqueous solutions in an open atmosphere. To obtain an intense pin-to-liquid alternating current discharge using a dielectric barrier, discharge characteristics, including the area and shape of a ground-plate-type electrode, were investigated after filling the vessel with equivalent amounts of water. Consequently, as the area of the ground electrode increased, the discharge current became stronger, and its timing became faster. Moreover, we proposed that the pin-to-liquid DBD reactor could be used to decompose phosphorus compounds in water in the form of phosphate as a promising pretreatment method for monitoring total phosphorus in water. The decomposition of phosphorus compounds using the pin-to-liquid DBD reactor demonstrated excellent performance—comparable to the thermochemical pretreatment method—which could be a standard pretreatment method for decomposing phosphorus compounds in water.

Highlights

  • Atmospheric pressure (AP) plasmas are ionized gaseous collections containing multiple charged particles, excited species, and radicals that are highly chemically reactive but have a very short lifespan [1,2,3,4,5]

  • The discharge current waveform demonstrated that each discharge occurred during the rising and falling periods of the voltage waveform, which indicated that discharges were stably produced even when the pin-type electrode served as an anode and a cathode

  • Considering that the intensity of the discharge current generated in each cycle was constant, it was confirmed that the pin-to-liquid dielectric barrier discharge (DBD) system was very stable

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Summary

Introduction

Atmospheric pressure (AP) plasmas are ionized gaseous collections containing multiple charged particles, excited species, and radicals that are highly chemically reactive but have a very short lifespan [1,2,3,4,5]. The pin-to-plate electrode configuration allows for facile air discharge without additional gas discharge owing to the pointed end of the pin-shape electrode inducing a localized electric field enhancement. As these devices have a simple structure and are easy to control, multiple modified devices with pin-toplate electrode configurations, such as pin-to-plate dielectric barrier discharge (DBD) and pin-to-liquid discharge, have been reported [16,17,18,19]. The water placed on the metal plate is treated with air plasma using pin-to-plate discharge

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