Potato-on-rod like of Z-scheme plasmon Ag2CrO4-Ag2Mo2O7 heterojunction nanophotocatalyst with high stability and accelerated photo-degradation evolution of organic contaminants

Abstract

The shocking increase of resistant dye pollutants in the environment and their harmful effects has become a potential threat to the ecosystem. In the current work, the novel and highly efficient potato-on-rod-like Z-scheme plasmon Ag2CrO4–Ag2Mo2O7 heterojunction nano-photocatalyst was synthesized by precipitation method to photodegrade different organic dyes under artificial sunlight. The required analysises were carried out to characterize nanophotocatalysts. FESEM and TEM results showed the placement way of potato-like Ag2CrO4 between/on rod-like Ag2Mo2O7 which was leading to suitable structure and surface morphology. Besides, the morphology observations released the meso-/macroporous potato-on-rod like architecture self-assembled by nanoparticles. DRS analysis also confirmed two band gap energies of 2.55 and 1.72 eV in Ag2CrO4–Ag2Mo2O7 (3:1) resulting from forming a heterojunction structure and the plasmon Ag. Ag2CrO4–Ag2Mo2O7 (3:1) nanophotocatalyst exhibited the most remarkable activity in the photodegradation of 10 mg/L 2-naphthol orange (97.8%), 10 mg/L rhodamine B (99.7%), 10 mg/L crystal violet (98.9%), and 10 mg/L methyl orange (56.1%) with a catalyst dosage of 0.1 gr for about 90 min. The appropriate energy band gap, the formation of the heterostructure, the presence of meso (0.0038 cm3/g) and macro (0.0044 cm3/g) holes, and pore diameter at about 17.2 nm based on BET-BJH analysis that facilitated the penetration of pollutant molecules, increased pollutant adsorption and demonstrated stunning capability of efficient light harvesting, the reason was electron-hole pairs recombination rate reduction. Moreover, the fabricated samples showed tremendous catalyst constancy and reusability even after the fourth run. Results have shown the remarkable photocatalytic activity under visible light and provide an environment-friendly and green strategy to overcome the challenges of organic pollutants present in aqueous solutions.