Abstract

Polyhalite, K 2Ca 2Mg (SO 4) 4-2H 2O, is an important mineral in many evaporites. Although its use for K-Ar dating has never been investigated, our results indicate that it is a very useful mineral for dating events ranging from the time of potash mineralization to any younger events which may have affected the evaporite. Five K-Ar dates on pure polyhalite, including two from included material and from beds distorted by the formation of a rubble chimney, yield dates between 198 and 216 Myp, in good agreement with Rb-Sr dates and the diagenetic age of the potash deposits from the same rocks. Two polyhalites mixed with sylvite gave lower dates (154 and 174 Myr) which is to be expected because of radiogenic 40Ar loss from the sylvite phase. One polyhalite, formed after the intrusion of a 31 Myr lamprophyre dike, yielded 21 Myr. Collectively our results indicate that pure polyhalite is satisfactory for K-Ar dating and may provide critical age information in studies of the geologic history of the evaporite sequences.

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