Abstract

The diagenesis of Permian siliciclastic sedimentary rocks of the Denison trough is interpreted in terms of evolving pore-water composition related to the burial history of the basin. In the sandstones, early precipitation of pyrite, siderite, and grain-rimming illite-smectite was followed by development of quartz overgrowths that incorporated silica released by pressure solution, recrystallization of lithics, and smectite/illite reaction. Later, as the sequence reached maximum burial during the Late Triassic, strongly {18}O-depleted siderite and ankerite, which incorporated iron and magnesium liberated by leaching of detrital mafic minerals and continuing smectite/illite reaction, precipitated from connate pore water expelled upward from the underlying, overpre sured continental Reids Dome beds. This implies the existence of significant cross-formational pore-water flow prior to and during attainment of maximum burial. Regional Late Triassic to earliest Jurassic compression resulted in major uplift and exposure of the Permian sequence. Attendant strata-concordant invasion of meteoric water led to labile grain and ferroan carbonate dissolution, and to the formation of strongly {18}O-depleted kaolinite and a second generation of quartz overgrowths. Later postdepositional events, which occurred during a second cycle of burial and uplift, include the precipitation of {18}O-depleted calcite and dawsonite, and hydrocarbon entrapment.

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