Post-eruptive process and products of volcanic rock alteration (transformation and synthesis of secondary products)

Abstract

The conditions of transformation of the primary material of extrusive rocks and the synthesis of secondary products during post-eruptive processes have been considered using the example of three large areas of presentday volcanism and hydrothermal activity in Kamchatka, viz., the Great Tolbachik Fissure Eruption of 1975–1976 (GTFE), the Karymskii Volcanic Center (eruption of 1996 in Lake Karymskii), and the Uzon volcanic-hydrothermal system. Post-eruptive transformation of rocks causes volcanic-hydrothermal lithogenesis and low-middle-temperature mineralization in areas of present-day contrast (basalt-andesite) volcanism in zones of crustal extension. Based on the permanent presence of a wide range of acid rocks, such as dacites, rhyolites, and pumices in the areas of Holocene basalt volcanism of Kamchatka, we concluded that in conditions of pre-rift crustal extension, acid volcanism is preceded by deep-seated differentiation (similar to liquation) of primary mantle melts with separation of fluids enriched in ore-forming elements, first of all Cu, Zn, Pb, As, Sb, and Hg. During volcanogenic-hydrothermal lithogenesis in the discharge areas of those fluid systems, the destruction and replacement of primary minerals of igneous rocks and formation of complex-composition metasomatites take place. Clay minerals are major components of metasomatites in subaqueous conditions. The role of microbiota in processes of volcanogenic-hydrothermal lithogenesis and occurrences of local mineralization was studied.