Abstract
A mass spectrometer with an ion source utilizing nearly monoenergetic electrons was used to measure appearance potentials of positive and negative ions in CCl3F. Kinetic energy measurements were made on the negative ions. The results have lead to values for the ionization potentials of CCl3, CCl2F, and CClF. The C–F and C–Cl bond energies have been determined from measurements on the negative fluorine and chlorine ions. A value is given for the electron affinity of the CCl3 radical.
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