Positive and negative ion composition measurements in the D- and E-regions during the 26 February 1979 solar eclipse

Abstract

Two rockets bearing quadrupole mass spectrometers capable of measuring both positive and negative ion composition were launched from Red Lake, Canada, during the solar eclipse. Both instruments had liquid helium cryopumps and shock-attaching conical samplers. The payloads also contained two Gerdien condensers to measure total positive and negative ion concentrations and ion mobilities. Attitude control systems aligned the payloads with the velocity vector throughout ascent and descent. The first rocket was launched so that the D-region was in darkness 35 ± 8 s on the upleg and about 150 ± 15 s on the downleg for the study of ionospheric decay processes. The second rocket was fired after totality into 75% solar illumination for the study of ionospheric recovery. The positive ion composition above 105 km exhibited a strongly increasing NO +/O 2 + ratio with time after second contact due to O 2 + charge transfer with NO and a sharply diminished ionization rate. However, in both nights, the ionization below 105 km was created mainly by energetic particle deposition as exemplified by the increased ion concentrations and the composition signatures of a particle event: asignificant enhancement of O 2 + below 105 km and large amounts of H 5O 2 + ions in the D-region which result from the O 2 + clustering scheme. H 5O 2 was the major ion in the upper D-region while H 7O + 3, H 9O 4 + and H 5O 2 + were dominant ions at lower altitudes. Numerous minor species were also detected. The negative ion distributions in both flights exhibited a distinct shelf at 83 ± 2 km, decreasing by more than an order of magnitude by 90 km and with minima near 75 km. In the 75–90 km range, a significant percentage of the negative ions had masses exceeding 160 a.m.u. Comparisons are made with prior negative ion measurements during similar daytime auroral zone absorption (AZA) events. Two striking characteristics of the precipitating particles were apparent from these and past observations in daytime AZA events: there is a near absence of low energy electrons capable of ionizing above about 105 km and there is'a significant spatial and/or temporal variability in the electron flux. This paper is devoted principally to a presentation of the ion composition measurements and associated uncertainties.