Porphyrin-based nanoporous materials for photocatalytic applications

Abstract

Alongside the unique photophysical properties, porphyrin derivatives play key roles in light harvesting of photosynthetic organisms. Due to their symmetrical structure, porphyrin derivatives serve as excellent building blocks for various porous materials, encompassing metal-organic frameworks, covalent organic frameworks, hydrogen-bonded organic frameworks, and amorphous porous organic polymers. These materials capitalize on the beneficial characteristics of porphyrins, such as their absorption capabilities, redox activity, and coordination chemistry, while leveraging the surface area and porosity inherent in porous frameworks. Porphyrin-based porous materials are explored for diverse applications including gas storage, energy storage, catalysis, separation, sensing, and environmental remediation. Owing to their excellent photophysical properties, these nanoporous materials are suitable for light harvesting and photocatalysis applications. This review emphasizes the potential of artificial light-harvesting catalysts based on porphyrin-based porous materials for solar energy applications. Researchers aim to optimize material properties and design innovative architectures to enhance performance in solar energy conversion and photocatalytic applications, making this a rapidly evolving field. Specific applications discussed in the review include photocatalytic CO2 reduction, photocatalytic water splitting, and perspectives on future developments in the field of porphyrin-based nanoporous materials for artificial light harvesting.