Porous cobalt phosphide nanoflakes supported on ordered mesoporous carbon for superior electrochemical performance supercapacitor and hydrogen evolution reaction

Abstract

In this study, we synthesized cobalt phosphate flake-like nanostructures anchored to the OMC matrix using a simple and cost-effective hydrothermal process followed by an environmentally friendly phosphidation process. The physicochemical characterization of the CoP@OMC composite indicated that the porous CoP nanoflakes made up of bundles of ultrathin nanosheets with an approximate thickness of 30nm are anchored on rod-like hexagonal OMC with a diameter of 110-140nm, allowing remarkable enhancement of mesoporosity and active surface area. The CoP@OMC composite was employed as a new material for modification of electrode surface used in supercapacitor and hydrogen evolution reaction (HER). Interestingly, CoP@OMC acquired a specific capacitance of 3182 Fg-1 at current density of 1Ag-1, in 6M KOH. Asymmetrical CoP@OMC//CB cell showed a capacity of 194 Fg-1 at the current density of 1Ag-1 with a maximum energy density of 77.9Whkg-1 and a power density of 17kWkg-1. CoP@OMC composite also showed an excellent HER performance with only 111mV overpotential to drive a current density of 10mAcm−2 and a low Tafel slope of 43.8mV dec−1 in 1M KOH. Therefore, CoP(OMC) as an environmentally friendly material with high efficiency and significant catalytic / electronic properties is expected to be a good candidate for future energy storage & conversion systems.