Abstract
In this work, a Suzuki cross-coupling procedure towards highly porous BINAP-based polymeric Ru-catalyst materials with tunable specific surface areas (SSAs) were synthesized and their stability towards reducing conditions was investigated. After the removal of Pd impurities by an oxidative treatment with H2O2/HCl, P=O reduction and metal loading, the resulting catalysts were employed for the base-free ruthenium-catalyzed decomposition of aqueous formic acid to CO2 and H2 with TOFs of up to 134000 h−1 and TONs up to 920000.
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