Pore-space characterisation of Tamusu mudstone based on FIB-SEM

Abstract

This study focuses on characterising the pore space in Tamusu mudstone, a preferred nuclear waste disposal host medium in China, using focused ion beam/scanning electron microscopy (FIB-SEM). The investigation is conducted at the mesoscale, with a sample volume of 7·96 × 9·16 × 10·00 μm3 and voxel sizes of 5 × 5 × 10 nm3. The findings reveal that the pores in Tamusu mudstone primarily exist at the nanoscale, typically within its mineral matrix or at interfaces with non-porous minerals. At the FIB/SEM-imaged scale, the pore space in the Tamusu mudstone is mainly unconnected, with an analysed porosity of approximately 3·5%. Pore characteristics within the specimen exhibit relative consistency within a box size of 6–8 μm. Furthermore, the pore paths in Tamusu mudstone exhibit a preferred orientation within the bedding plane, suggesting anisotropy in pore space, possibly attributed to changes in pore path orientation and tortuosity.