Abstract

The moisture retention curve of porous materials is often assumed to be independent of the process dynamics, i.e., of the drying/wetting rate. Experimental outcomes and pore-scale simulations put this assumption into question though. It has been shown that dynamic effects can significantly affect the moisture retention curve, which presents different behaviours, depending on whether it is determined at transient or steady-state conditions. The cause of this phenomenon is addressed as “dynamic effects” in the literature. While dynamic effects of the drainage process have been widely studied, the data concerning spontaneous imbibition are still quite limited. We attempt at reducing this lack of knowledge by modelling spontaneous imbibition in an artificial material sample represented by a pore network model. In our model, the liquid flow is described via the Hagen-Poiseuille equation, while a percolation algorithm controls the dynamics of liquid-gas interfaces through the network junctions. A dynamic contact angle between liquid water and pore surface is considered, depending on the velocity of the meniscus. Dynamic states are determined by linking the local capillary pressure to the local moisture content in the artificial material sample subject to spontaneous imbibition. Our investigation demonstrates that dynamic effects due to contact angle variations may have a major impact on the imbibition process.

Highlights

  • Moisture is often the critical factor when judging built structures’ durability and sustainability, for which the accurate understanding and reliable assessment of moisture transfer and storage in building materials are crucial

  • One observes a delay of the imbibition process with respect to the static variant, i.e., the capillary pressure and moisture saturation profiles are shifted to the left

  • This is consistent with the dynamic contact angle being larger than the static one, leading to a smaller capillary pressure and slower imbibition process

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Summary

Introduction

Moisture is often the critical factor when judging built structures’ durability and sustainability, for which the accurate understanding and reliable assessment of moisture transfer and storage in building materials are crucial. The moisture storage capability of porous materials during any imbibition or drainage process is described via the moisture retention curve, a mathematical correlation expressing the local capillary pressure as a function of the local moisture content. This correlation is often assumed to be independent of the imbibition/drainage speed, i.e., the (de)saturation rate. It has been shown that the (de)saturation rate can significantly affect the moisture retention curve. The cause of this phenomenon, still not fully explained, is addressed in the literature as “dynamic effects” on the moisture retention curve

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