Abstract

Mild and convenient method for deprotection and direct oxidative deprotection of silyl ethers to the corresponding hydroxy and carbonyl compounds is described using polyvinylpolypyrrolidone-bromine complex (PVPP-Br2). Selective oxidative deprotection of benzylic silyl ethers in the presence of primary aliphatic alcohols was also achieved at room temperature. Keywords: Polyvinylpolypyrrolidone, PVPP-Br2, deprotection, oxidative deprotection, TMS ethers, TES and TBDMS ethers

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.