Polyvinyl alcohol gel/micro-arc oxidation 3D-printed porous structural aluminium for oil-water separation

Abstract

Traditional oil-water separation membranes still face challenges in designing membrane structures and pore sizes. In this study, we successfully prepared a PVA@MAO 3D-Al material with an internal porous structure using 3D printing technology and micro-arc oxidation (MAO). Compared to the base 3D-Al material, the fabricated PVA@MAO 3D-Al exhibits excellent wear resistance, with an average friction coefficient reduced by 66% in dry friction and 22% in water lubrication. In electrochemical experiments, corrosion current density decreased by an order of magnitude, indicating higher stability of PVA@MAO 3D-Al in corrosive environments. In oil-water separation experiments, PVA@MAO 3D-Al achieved separation efficiencies exceeding 97% for mixtures of white oil, kerosene, liquid paraffin, and cyclohexane with water. Moreover, even after undergoing 600 cycles of reciprocating friction and exposure to various environmental solutions, the separation efficiency of PVA@MAO 3D-Al for white oil/water mixtures remained above 96%, demonstrating outstanding physical and chemical stability. This suggests that PVA@MAO 3D-Al is suitable for use in extremely harsh environments. This study introduces a simple and efficient approach to manufacturing oil-water separation membranes using 3D printing technology, coupled with MAO technology to enhance the base material's performance. The combination of these techniques opens up new avenues in the field of oil-water separation.