Abstract
In the title complex, [Na(C6H4NO4S2)(C10H20O5)], an irregular coordination sphere around Na+ is formed by the five O atoms of 15-crown-5 and the N and one O atom of the disulfonylimide 1,3,2-benzodithiazole 1,1,3,3-tetraoxide(1−). In one C—C—O segment of the polyether ring, two successive gauche torsion angles of the same sign constitute a conformational corner.
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