Abstract

We present herein the synthesis and structural characterization of a novel, recyclable and microwave stable polymeric reagent prepared by anchoring bromoderivative of oxazolidone into the 3D matrix of divinylbenzene crosslinked polystyrene and its application for the bromination of alkenes, activated aromatic compounds and for the α-halogenation of ketones under microwave irradiation. The advantages of this protocol include a simple workup procedure, high product yield, shorter reaction time as well as solvent-free reaction pathway. Besides, this new resin was stable under standard laboratory conditions and can be kept for several months without any significant loss of activity.

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