Abstract

Stable and non-hygroscopic polystyrene supported aluminium triflate (Ps-<TEX>$Al(OTf)_3$</TEX>), which is prepared easily from cheap and commercially available compounds was found to be an environmentally friendly heterogeneous catalyst for Friedel-Crafts acylation of arenes using acid chlorides in the absence of solvent under mild reaction conditions. The catalyst can be reused up to five times after simple washing with dichloromethane.

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