Polypyrrole-mediated construction of superhydrophobic photo/electro thermal composite fabric for efficient crude oil dehydration and recovery

Abstract

During crude oil extraction, transportation, and oil spill recovery, rapid and effective removal of water from crude oil is a great challenge. Super-hydrophobic functional membranes with electrothermal/photothermal effects are considered to be an effective method. However, simply polymerizing photothermal/electrothermal nanomaterials on the membrane surface will lead to unstable thermal effects and easy shedding. Therefore, in this study we propose the synthesis of a novel superhydrophobic electrothermal/photothermal Nylon fabric (PSPPNF) by an innovative in situ polymerization method of Pyrrole (Py), to realize efficient viscosity reduction and dehydration of crude oil. In particular, by controlling FeCl3 solution from solid (−18 °C) to liquid state (0 °C), Py was polymerized on the fabric surface by slow oxidative process, which can effectively solve the problem of pore blocks to obtain a stable-conductive layer on the NF surface. The PSPPNF surface temperature can reach 80 °C under 1 kW m−2 sunlight intensity or by inputting 30 V, which brings a separation efficiency of 97 % for high-viscous crude oil/water mixture. We systematically analyzed the effects of PSPPNF with different pore sizes and oils with different viscosities on the separation flux, as well as the effects of the thermal properties of the membranes under different illumination conditions and voltages on crude oil permeation. Additionally, the PSPPNF combined with the roller can realize all-weather available crude oil spill recovery under solar and electrical energy. This work provides new insights into membrane materials that can realize the efficient dehydration and recovery of crude oil for day-night alternation and complex environments.