Polypropylene/carbon nanotube nanocomposite fibers: Process–morphology–property relationships

Abstract

AbstractThis study is focused on aligning carbon nanotubes in polypropylene matrix by melt spinning. Two different weight percentages (0.5% and 1.0%) of nanotubes were used for the synthesis of the nanocomposite fibers. The effect of the nanotubes on the crystallization and mechanical behavior of polypropylene as well as the effect of draw ratio on the nanocomposite morphology and properties is also discussed. Correlation of fiber morphology and nanotube alignment was done using differential scanning calorimetry, wide‐angle X‐ray diffraction, and transmission electron microscopy. Significant improvement in tensile modulus and tensile strength were observed, which is characteristic of a highly aligned nanotube system. A substantial vincrease in the onset of decomposition was observed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3844–3850, 2007