Polyolefin-based electrospun fibrous matrices embedded with magnetic nanoparticles for effective removal of viscous oils.

Abstract

In this work, we present a poly (ethylene-co-1-octene)-based fibrous matrix prepared via electrospinning for highly efficient removal of viscous oils. The sorbent consisting of linear low density polyethylene (LLDPE) allows selective absorption of crude oil spills at the water surface without the need for additional isolation of the matrix prior to the refining process. Moreover, the high specific pore volume of the LLDPE sorbent with uniform fibrous morphology was shown to enable the sorbent reach 81.5±5.9% of its equilibrium absorption capacity within 5min. Furthermore, magnetic nanoparticles (MNP) are incorporated into each fiber comprising the matrix to facilitate the recovery process via external magnetic field without altering the intrinsic absorption capacity. We envision that these sorbents offer a sustainable route for the quick and thorough clean-up of spilled oil due to their high absorption capacity, fast absorption rate, ease of recovery, and absence of secondary waste.