Polynuclear heterometallic cadmium(II)/silver(I) phenylthiolates: Syntheses and structures of [Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4] and [Cd3(OMe)2(μ-SPh)4(μ3-SPh)8Ag8(μ-dppp)4] (dppp = 1,3-bis(disphenylphosphino)propane)

Chao Xu,Taike Duan,Wa-Hung Leung,Jing-Jing Zhang,Qun Chen,Qian-Feng Zhang

doi:10.1016/j.inoche.2011.11.012

Polynuclear heterometallic cadmium(II)/silver(I) phenylthiolates: Syntheses and structures of [Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4] and [Cd3(OMe)2(μ-SPh)4(μ3-SPh)8Ag8(μ-dppp)4] (dppp = 1,3-bis(disphenylphosphino)propane)

Chao Xu, Taike Duan + Show 4 more

https://doi.org/10.1016/j.inoche.2011.11.012

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Journal: Inorganic Chemistry Communications	Publication Date: Nov 15, 2011
Citations: 4

#Molar Ratio #Neutral Cluster + Show 5 more

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Abstract

Abstract Reaction of [Me4N]2[Cd(SPh)4] and [Ag(PPh3)2NO3] (molar ratio = 1:1) in MeOH/CH2Cl2 (1:1) followed by recrystallization from DMF/Et2O yielded a neutral heptanuclear cluster, [Cd3(μ-SPh)6(μ3-SPh)4Ag4(PPh3)4] (1), while interaction of [Me4N]2[Cd(SPh)4] with AgNO3 and dppp (molar ratio = 4:6:3) gave a neutral undecanuclear cluster [Cd3(OMe)2(μ-SPh)4(μ3-SPh)8Ag8(μ-dppp)4] (2). Crystal structures and photoluminescent properties of the two clusters in solid state were reported.

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