Polymorphism and cocrystal salt formation of 2-((2,6-dichlorophenyl)amino)benzoic acid, harvest of a second form of 2-((2,6-dimethylphenyl)amino)benzoic acid, and isomorphism between the two systems

Abstract

Isomorphism and isostructurality were observed between form I of 2-((2,6-dimethylphenyl)amino)benzoic acid and its analog 2-((2,6-dichlorophenyl)amino)benzoic acid, which suggests double Cl–CH3 exchange also leads to structural similarity.