Polymorphic phase transition in CoCrNi medium-entropy alloy under impact loadings

Abstract

Polymorphic phase transition in metallic materials under high pressure is a critical aspect of dynamic properties and has been attracting a great interest. Despite the extensive researches have been made on understanding of this phase transition in traditional single-principal element alloys, little is known about the phase transition in recently emergent multi-principal medium and high entropy alloys, especially compressed under high strain rates. In this work, based on molecular dynamic simulations, three impact loading strategies with distinct loading paths, such as single-shock, double-shock and ramp-wave loading are carried out on the single crystalline CoCrNi medium-entropy alloy (MEA) to investigate the phase transition under high strain-rate compression. Careful characterizations show that the phase transition of CoCrNi MEA is loading-path dependent, as evidenced by the significant differences in macroscopic pressure evolution and microscopic structural phase transition among the samples under various thermodynamic paths. An intriguing pressure “overshoot” is found and demonstrated as the characteristic of the critical structural phase transition from face-centered cubic (FCC) structure to hexagonal-close-packed (HCP) structure mediated by body-centered cubic (BCC) like clusters. We show that such loading-path dependence is attributed to the strain rate and temperature rise in the loading process, which control the evolution of microstructure and deformation field. The inherent correlation between the atomistic process of phase transition and loading strategies results in polymorphic phase transition under high strain rates. These findings shed new light on the nature of impact phase transition of multi-principal alloys.