Polymer-Stabilized Cholesteric Liquid Crystal Films with Double Reflection Bands Prepared Based on the Competition between Photopolymerization and Photoisomerization.

Abstract

Composite colors have been widely found in nature. Herein, polymer-stabilized cholesteric liquid crystal (PSCLC) films with composite structural colors were prepared through a one-step photopolymerization approach. The CLC mixtures were prepared using a mixture of acrylates and a mixture of two chiral dopants. One of the chiral dopants is polymerizable, and the other one is photoisomerizable. After photopolymerization, the PSCLC films with double Bragg reflection bands were obtained on the surface of a substrate. The competition between the photopolymerization of the acrylates and the photoisomerization of the chiral dopant was proposed to drive the formation of the double reflection bands. Without oxygen inhibition, the polymerization of the acrylates near the substrate surface was carried out. However, due to oxygen inhibition, the polymerization of the acrylates near the air was retarded. Then, the photoisomerization of the chiral dopant was carried out prior to the polymerization of the acrylates. The wavelengths of the double reflection bands were tunable by changing the concentrations of the acrylates and chiral dopants and the polymerization temperature. Colorful patterns with composite structural colors were prepared, which were suitable for decoration and anti-counterfeiting.