Abstract
The copolymer poly(acrylonitrile-co-styryl isocyanate) was prepared directly in bulk by radical initiation either from the monomer pair acrylonitrile–cinnamoyl azide or from the pair acrylonitrile–styryl isocyanate. The copolymerization parameters, calculated by the conventional scheme, are r1, = 3.5 ± 0.5; r2 = 0 ± 0.5, for the first pair and r1 = 9 ± 0.5; r2 = 0 ± 0.5 for the second pair. The basic physical properties (solubility, intrinsic viscosity, and thermal behavior) of the new copolymer were determined and the chemical reactions of the isocyanate group with alcohol and with dimethylformamide were investigated.
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