Abstract
The formation and decay of cyclic oligomers during hydrolytic polymerization, cationic polymerization, and autocatalytic polymerization of 6-hexanelactam carried out at 260 C was followed by means of the high performance liquid chromatography (HPLC) analysis of portions extracted with methanol from the polymerization products. It was proved that the type of initiation system substantially affects the formation mechanism of cyclic oligomers. In the autopolymerization of 6-hexanelactam, the concentration of cyclic oligomers as a function of monomer conversion confirms a change of the predominant reaction mechanism during the polymerization.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
