Abstract

Abstract Effective transformation of a biomass-derived heteroaromatic compound furfural into conjugated polymer is described. Furylthiazole composed of furan and thiazole rings is employed as a monomer and palladium-catalyzed C–H coupling polycondensation furnishes the corresponding formal alternating copolymer. The coupling reaction in the presence of Pd(OAc)2 (20 mol %) as a catalyst undergoes polymerization in >99% yield with Mn = 10.2 × 103.

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