Abstract
We have tailored a new composite based on a porous silica matrix and poly(diacetylene-bis-(toluenesulfonide)). The filling of the sample was characterized by energy-dispersive X-ray (EDX) and Raman scattering spectroscopies. Raman scattering, in the polarized mode, was used to check the orientation of the macromolecules in the polymer single crystal before using these data to probe the polymer chain orientation inside the nanocomposite. We have found that polymer chains are oriented along the pore axis with a fairly high conjugation length.
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