Abstract
AbstractCopolymers of 3,4‐dihydro‐2H‐pyran‐2‐carboxyaldehyde (acrolein dimer) with phenyl isocyanate were obtained under several conditions. Infrared and NMR analyses showed that the isocyanate always reacted with acrolein dimer forming urethane linkages, not block units of isocyanate. An alternating copolymer was obtained from the copolymerization in the presence of anionic catalysts such as butyllithium at room temperature, irrespective of the monomer ratios employed. The isocyanate content in the copolymer prepared with an Al(C2H5)2Cl catalyst was increased by elevating polymerization temperature. The copolymerizability of aldehydes with the isocyanate depends upon the polarity of aldehyde group.
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