Abstract

Dissolution of vitreous arsenic selenide in some organic solvents (diethylamine, dimethylamine) and in alkaline solvent was investigated. Considerable swelling of As 2Se 3 in diethylamine, indicating the polymeric nature of this material, was revealed. The results of comparative studies of solving speed of pure As 2Se 3, of As 2Se 3 doped with I, Ge and Cu, as well as of materials with deviations from stoichiometric composition are interpreted proceeding from the concepts of joining or breaking up the macromolecules of As 2Se 3. The parallel studies of the curves of thermostimulated depolarization of the same materials disclose a connection between the energy spectrum of local states and the parameters of polymeric structure.

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