Abstract

AbstractMonomethacrylyldimethylglyoxime and dimethacrylyldimethylglyoxime were prepared by acylation of dimethylglyoxime with methacrylyl chloride. Monoallyldimethylglyoxime and diglycidyldimethylglyoxime were prepared by alkylation of dimethylglyoxime sodium salt with allyl bromide and epichlorohydrin, respectively. The monomethacrylyl derivative formed a copolymer with methyl methacrylate and the dimethacrylyl derivative yielded a homopolymer. Nickel chelates could be formed from both polymers. Diglycidyldimethylglyoxime was easily copolymerized with a number of diamines. A polymer formed as a by‐product from the preparation of the diglycidyldioxime was easily cured with m‐phenylenediamine.

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