Abstract
In the title compound, [Li(C12H10O2P)(C4H8O)]n, the O atoms of adjacent and bridging diphenylphosphinate ligands and that from a tetrahydrofuran (thf) molecule are arranged in a tetrahedral manner around the Li atoms, resulting in a one-dimensional array (parallel to the a axis) of alternate eight-membered and rectangular planar four-membered rings [the two Li—O distances are 1.962 (6) and 1.991 (6) A, and the Li—O—Li and O—Li—O angles are 88.3 (2) and 91.7 (2)°, respectively]. The Li—O distances for the O atoms of the phosphinate ligand are 1.992 (6) (for the μ-O atom) and 1.897 (6) A, and the distance from Li to the O atom of the thf ligand is 2.028 (6) A.
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