Abstract
Polymer chelates of epoxy based polyester ligands containing oxine as pendent group, have been prepared with different metal ions like Zn +2 , Cu +2 , Ni +2 , and Co +2 . These novel polymer ligands have been synthesized by condensation of 5-chloromethyl-8-quinolinol hydrochloride respectively with epoxy based prepolyhydroxy ester of succinic acid (EPPE-Su) and of sebacic acid (EPPE-Se) in presence of base catalyst. All these polymer ligands and polymer chelates are characterized by elemental analyses, IR and diffuse reflectance spectral studies for their structure determination. The thermal stability of all polymer chelates have been estimated by thermogravimetric analyses (TGA). Besides this, all the polychelates have also been characterized for their magnetic susceptibility and metal to ligand stoichiometry estimation.
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More From: International Journal of Polymeric Materials and Polymeric Biomaterials
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