Abstract
The germyl borate 1 was prepared by the reaction of triphenylborane with an excess of unsolvated triethylgermyllithium in a hexane/benzene mixed solvent. The polymeric structure of 1 was observed in the solid state and in a hydrocarbon solvent. The lithium atoms were located near the center of the benzene ring and interacted with the neighboring borate molecules by the Li +–π interaction. The polymeric structure was destroyed by the addition of MeOH, however, 1 was coordinated by three MeOH molecules to form the dimeric structure without alcoholysis reaction.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
